Inductive Field Effect:-
The 'Inductive Effect' is an electron delocalization effect via σ bonds, the transmission of charge through a chain of atoms in a molecule that arises due to the difference in electronegativities of atoms in a molecules this induced effect is called inductive effect.
For Example,
In Propane the C–C–C bond has no polarity, so no Inductive effect because it connects three equivalent atoms, with identical electronegativities. The organic compound like C-C-C-Cl presence of a more electronegative atom attached to one of the carbon atoms will lead to bond polarization. The C–C bond in chloroproane is polarized by the presence of the electronegative chlorine atom.
There is two types of Inductive Effect:-
The type of inductive effect depends on
their strength of electron withdrawing or electron releasing nature with
respect to hydrogen.
- +I Effect or Positive Inductive Effect
- -I Effect Or Negative Inductive Effect
+I Effect:-
The Groups that have electron releasing
nature towards carbon are
termed as +I groups and the groups or atoms
are denoted by +I effect in organic compound.
Examples:- Decreasing order
of their +I effect
C(CH3)3 >
CH(CH3)2 >
CH2CH3 >
CH3 > H
Why alkyl groups are showing +I
effect...?
The C-H bond is practically considered as non-polar, because
partial (+) charge on hydrogen atom and partial (-) charge on carbon atom.
Therefore each hydrogen atom acts as electron donating group and carbon acts as
electron withdrawing group. This cumulative effect turns the alkyl moiety into
an electron donating group.
-I Effect:-
The Groups that have electron withdrawing nature towards carbon are termed as -I groups and the groups or atoms are denoted by -I effect in organic compound.
NH3+ > NO2 > CN >
SO3H > CHO > CO
> COOH > COCl > CONH2 > F >
Cl > Br > I > OH > OR > NH2 > C6H5 > H
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